Tangential and normal components of acceleration
Acceleration split into a part along velocity (a_T, speeding up/slowing down) and a part perpendicular to it (a_N, turning).
Acceleration splits into a_T\mathbf{T}+a_N\mathbf{N}, a part parallel to velocity and a part perpendicular to it — the only two directions available, since the \mathbf{B}-coefficient is always exactly 0. a_T=\dfrac{\mathbf{r}'\cdot\mathbf{r}''}{|\mathbf{r}'|} changing sign is what "speeding up" versus "slowing down" means in vector terms; a_N=\dfrac{|\mathbf{r}'\times\mathbf{r}''|}{|\mathbf{r}'|}=\kappa v^2 is always \ge0 and vanishes only where the path is momentarily straight (\kappa=0) or momentarily stopped (v=0).
Examples
For \mathbf{r}(t)=\langle t, t^2, 0\rangle at t=1: a_T = 4/\sqrt5 \approx 1.79 and a_N = 2/\sqrt5 \approx 0.89.
In a car, a_T is the push into your seatback from speeding up or braking, while a_N is the sideways push toward the door as you round a curve.
See also