Residue
\operatorname{Res}_{z=z_0} f = a_{-1}, the coefficient of (z-z_0)^{-1} in the Laurent series at z_0.
The residue of f at an isolated singularity z_0, written \operatorname{Res}_{z=z_0} f, is the coefficient a_{-1} of (z-z_0)^{-1} in f's Laurent series there. It is singled out from every other Laurent coefficient because it alone survives integration -- \oint_C f(z)\,dz = 2\pi i\,\operatorname{Res}_{z=z_0} f for a small positively oriented circle C around z_0 containing no other singularity, since every other power of (z-z_0) integrates to zero around a closed loop.
Examples
For f(z)=e^z/z^2, the Laurent series at 0 is \frac1{z^2}+\frac1z+\frac12+\cdots, so \operatorname{Res}_{z=0}f=1.
A function analytic at z_0 (no singularity there at all) has residue 0 at z_0, since its Laurent series is just its Taylor series, with no (z-z_0)^{-1} term.